Enzyme-Based Organic Synthesis. Cheanyeh Cheng

Enzyme-Based Organic Synthesis - Cheanyeh Cheng


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arene such as naphthalene; and biphenyl as the starting material to produce various kinds of cis‐1,2‐dihydrodiols that in turn have been used as chiral synthons for the generation of valuable biologically active products through sequential chemoenzymatic steps. The following examples show the wide applications of this synthetic strategy.

Chemical reaction depicting catabolic pathways of monosubstituted benzene to diol via cis-dihydrodiol. Chemical reaction depicting chemoenzymatic preparation of pancratistatin analogs. Chemical reaction depicting whole-cell fermentation of methyl 2-iodobenzoate for organic synthesis. Chemical reaction depicting toluene dioxygenase catalyzed cis-dihydroxylation of phenols toward catechol, cyclohexenone cis-diol, and o-quinol dimmer metabolites. Chemical reaction depicting naphthalene dioxygenase catalyzed cis-dihydroxylation of naphthalene. Chemical reaction depicting regioselective oxidation <hr><noindex><a href=Скачать книгу