Polar Organometallic Reagents. Группа авторов

Polar Organometallic Reagents - Группа авторов


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chemistry as accessed by ate complexes. A range of ate complexes are discussed, but the chapter opens, appropriately enough, with work done in Sendai in the early 1990s. Initial discussion of sterically demanding tetramethylzincate in a range of transformations eventually shifts to the advent of organoamidozincates that are structurally covered in earlier chapters. From there, the evolution of aluminate and cyanocuprate congeners follows naturally. Again, structural aspects of these species feature elsewhere, but the discussion here focuses on their potential in aromatic derivatization. The chapter also continues a theme from the previous one. Efforts to exert control over the reactivity of boryl anions through ate complexes are presented in the context of novel nucleophilic boration. Lastly, Chapter 9 finishes the book as it started, looking at organocopper compounds. Copper‐mediated processes are well established, prompting much organocopper structural chemistry. Whereas efforts have often focused on alkynyl‐ and arylorganocopper complexes, the emphasis here is instead on traditionally unstable mono‐alkenyl and butadienylcopper compounds. The potential of steric, coordinative and synergistic strategies for preventing decomposition are examined.

      Overall, this book seeks to bring the reader up‐to‐date with developments in the field of modern polar organometallic chemistry, particularly in the context of the emergent areas of synergic and cooperative species. The recent advances in our understanding of the operation of these systems are presented, but the evolution of the area is described, offering a context and explaining the need and rationale for the advent of new reagents. The hope is that this is done in a way that makes the text accessible to students as well as academics and industrial scientists, arming them with a broad understanding of how these systems present new opportunities to the synthetic chemist.

      A. E. H. Wheatley Cambridge, UK

      M. Uchiyama Tokyo, Japan

      List of Contributors

      Alistair M. Broughton Yusuf Hamied Department of Chemistry University of Cambridge Cambridge, UK

      Andrew E. H. Wheatley Yusuf Hamied Department of Chemistry University of Cambridge Cambridge, UK

      Andrew J. Peel Yusuf Hamied Department of Chemistry University of Cambridge Cambridge, UK

      Andrew S. S. Wilson Department of Chemistry University of Bath Claverton Down, UK

      Anne‐Frédérique Pécharman Department of Chemistry University of Bath Claverton Down, UK

      Antoine Buchard Department of Chemistry University of Bath Claverton Down, UK

      Chao Wang Graduate School of Pharmaceutical Sciences The University of Tokyo Tokyo, Japan

      Eva Hevia Department für Chemie, Biochemie und Pharmazie Universität Bern Bern, Switzerland

      Frances N. Singer Department of Chemistry University of Bath Claverton Down, UK

      Keiichi Hirano Graduate School of Pharmaceutical Sciences The University of Tokyo Tokyo, Japan

      Leonie J. Bole Department für Chemie, Biochemie und Pharmazie Universität Bern Bern, Switzerland

      Liang Liu College of Chemistry Peking University Beijing, China

      Mamta Bhandari Department of Chemical Sciences Indian Institute of Science Education and Research Mohali India

      Masanobu Uchiyama Graduate School of Pharmaceutical Sciences The University of Tokyo Tokyo, Japan

      Research Initiative for Supra‐Materials (RISM)

      Shinshu University

      Nagano, Japan

      Masanori Shigeno Graduate School of Pharmaceutical Sciences Tohoku University Sendai, Japan

      Michael S. Hill Department of Chemistry University of Bath Claverton Down, UK

      Robert E. Mulvey WestCHEM, Department of Pure and Applied Chemistry University of Strathclyde Glasgow, UK

      Sandeep Rawat Department of Chemical Sciences Indian Institute of Science Education and Research Mohali India

      Sanjay Singh Department of Chemical Sciences Indian Institute of Science Education and Research Mohali India

      Sharanappa Nembenna School of Chemical Sciences National Institute of Science Education and Research Bhubaneswar India

      Stuart D. Robertson WestCHEM, Department of Pure and Applied Chemistry University of Strathclyde Glasgow, UK

      Yoshinori Kondo Graduate School of Pharmaceutical Sciences Tohoku University Sendai, Japan

      Zhenfeng Xi College of Chemistry Peking University Beijing, China

      Acknowledgements

      The editors wish to thank John Wiley & Sons for the opportunity to publish this work. Our sincere thanks go to Sarah Higginbotham for proposing and supporting the idea of a book covering the recent advances in the field of polar organometallics. We are also grateful to Emma Strickland and the handling editors, particularly Katrina Maceda, for their constant support and advice. Finally, we would thank the chapter authors for contributing their expertise and time, without which this book could not have happened.

       Masanori Shigenoa, Andrew J. Peelb, Andrew E. H. Wheatleyb, and Yoshinori Kondoa

       a Graduate School of Pharmaceutical Sciences, Tohoku University, Sendai, Japan

       b Yusuf Hamied Department of Chemistry, University of Cambridge, Cambridge, UK


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