Catalytic Asymmetric Synthesis. Группа авторов

Catalytic Asymmetric Synthesis - Группа авторов


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intermediate, followed by a 6‐endo cyclization to yield tetrahydroquinoline derivatives (Scheme 2.13). An enantioselective C–H activation was proposed.

Schematic illustration of Friedel-Crafts alkylation reaction with ketimines and indoles (a) and furans (b).

      Source: Based on [48]

      ) and furans (b) (

      Source: Based on [49]).

Schematic illustration of Friedel-Crafts alkylation reaction between N-H trifluoromethylated ketimines and pyrroles (a) and 4,7-dihydroindole (b).

      Source: [51, 52]

      ) and 4,7‐dihydroindole (b) (

      Source: Based on [53]).

Schematic illustration of Friedel-Crafts alkylation reaction between indole and N-H trifluoromethylated iminoesters.

      Source: Based on [54].

Schematic illustration of internal redox reaction. Schematic illustration of radical addition to imines.

      2.3.2. Reactions with Carbonyl Compounds and Oxonium Salts

Schematic illustration of torgov reaction. Schematic illustration of prins cyclization.

      Source: Based on [58].

Schematic illustration of intramolecular carbonyl-ene reaction.

      Source: Based on [59].

      Source: Based on [61].

Schematic illustration of kinetic resolution of homoaldols.

      Source: Based on [20].


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