Volcanic Islands. Darwin Charles
PRODUCED BY THE FLOWING OF THE SUPERINCUMBENT BASALTIC LAVA OVER THE CALCAREOUS DEPOSIT.
These effects are very curious. The calcareous matter is altered to the depth of about a foot beneath the line of junction; and a most perfect gradation can be traced, from loosely aggregated, small, particles of shells, corallines, and Nulliporae, into a rock, in which not a trace of mechanical origin can be discovered, even with a microscope. Where the metamorphic change has been greatest, two varieties occur. The first is a hard, compact, white, fine-grained rock, striped with a few parallel lines of black volcanic particles, and resembling a sandstone, but which, upon close examination, is seen to be crystallised throughout, with the cleavages so perfect that they can be readily measured by the reflecting goniometer. In specimens, where the change has been less complete, when moistened and examined under a strong lens, the most interesting gradation can be traced, some of the rounded particles retaining their proper forms, and others insensibly melting into the granulo-crystalline paste. The weathered surface of this stone, as is so frequently the case with ordinary limestones, assumes a brick-red colour.
The second metamorphosed variety is likewise a hard rock, but without any crystalline structure. It consists of a white, opaque, compact, calcareous stone, thickly mottled with rounded, though regular, spots of a soft, earthy, ochraceous substance. This earthy matter is of a pale yellowish- brown colour, and appears to be a mixture of carbonate of lime with iron; it effervesces with acids, is infusible, but blackens under the blowpipe, and becomes magnetic. The rounded form of the minute patches of earthy substance, and the steps in the progress of their perfect formation, which can be followed in a suit of specimens, clearly show that they are due either to some power of aggregation in the earthy particles amongst themselves, or more probably to a strong attraction between the atoms of the carbonate of line, and consequently to the segregation of the earthy extraneous matter. I was much interested by this fact, because I have often seen quartz rocks (for instance, in the Falkland Islands, and in the lower Silurian strata of the Stiper-stones in Shropshire), mottled in a precisely analogous manner, with little spots of a white, earthy substance (earthy feldspar?); and these rocks, there was good reason to suppose, had undergone the action of heat, – a view which thus receives confirmation. This spotted structure may possibly afford some indication in distinguishing those formations of quartz, which owe their present structure to igneous action, from those produced by the agency of water alone; a source of doubt, which I should think from my own experience, that most geologists, when examining arenaceo-quartzose districts must have experienced.
The lowest and most scoriaceous part of the lava, in rolling over the sedimentary deposit at the bottom of the sea, has caught up large quantities of calcareous matter, which now forms a snow-white, highly crystalline basis to a breccia, including small pieces of black, glossy scoriae. A little above this, where the lime is less abundant, and the lava more compact, numerous little balls, composed of spicula of calcareous spar, radiating from common centres, occupy the interstices. In one part of Quail Island, the lime has thus been crystallised by the heat of the superincumbent lava, where it is only thirteen feet in thickness; nor had the lava been originally thicker, and since reduced by degradation, as could be told from the degree of cellularity of its surface. I have already observed that the sea must have been shallow in which the calcareous deposit was accumulated. In this case, therefore, the carbonic acid gas has been retained under a pressure, insignificant compared with that (a column of water, 1,708 feet in height) originally supposed by Sir James Hall to be requisite for this end: but since his experiments, it has been discovered that pressure has less to do with the retention of carbonic acid gas, than the nature of the circumjacent atmosphere; and hence, as is stated to be the case by Mr. Faraday, masses of limestone are sometimes fused and crystallised even in common limekilns. (I am much indebted to Mr. E.W. Brayley in having given me the following references to papers on this subject: Faraday in the "Edinburgh New Philosophical Journal" volume 15 page 398; Gay-Lussac in "Annales de Chem. et Phys." tome 63 page 219 translated in the "London and Edinburgh Philosophical Magazine" volume 10 page 496.) Carbonate of lime can be heated to almost any degree, according to Faraday, in an atmosphere of carbonic acid gas, without being decomposed; and Gay-Lussac found that fragments of limestone, placed in a tube and heated to a degree, not sufficient by itself to cause their decomposition, yet immediately evolved their carbonic acid, when a stream of common air or steam was passed over them: Gay-Lussac attributes this to the mechanical displacement of the nascent carbonic acid gas. The calcareous matter beneath the lava, and especially that forming the crystalline spicula between the interstices of the scoriae, although heated in an atmosphere probably composed chiefly of steam, could not have been subjected to the effects of a passing stream; and hence it is, perhaps, that they have retained their carbonic acid, under a small amount of pressure.
The fragments of scoriae, embedded in the crystalline calcareous basis, are of a jet black colour, with a glossy fracture like pitchstone. Their surfaces, however, are coated with a layer of a reddish-orange, translucent substance, which can easily be scratched with a knife; hence they appear as if overlaid by a thin layer of rosin. Some of the smaller fragments are partially changed throughout into this substance: a change which appears quite different from ordinary decomposition. At the Galapagos Archipelago (as will be described in a future chapter), great beds are formed of volcanic ashes and particles of scoriae, which have undergone a closely similar change.
THE EXTENT AND HORIZONTALITY OF THE CALCAREOUS STRATUM.
(FIGURE 2: SIGNAL POST HILL. (Section with A low and C high.)
A. – Ancient volcanic rocks.
B. – Calcareous stratum.
C. – Upper basaltic lava.)
The upper line of surface of the calcareous stratum, which is so conspicuous from being quite white and so nearly horizontal, ranges for miles along the coast, at the height of about sixty feet above the sea. The sheet of basalt, by which it is capped, is on an average eighty feet in thickness. Westward of Porto Praya beyond Red Hill, the white stratum with the superincumbent basalt is covered up by more recent streams. Northward of Signal Post Hill, I could follow it with my eye, trending away for several miles along the sea cliffs. The distance thus observed is about seven miles; but I cannot doubt from its regularity that it extends much farther. In some ravines at right angles to the coast, it is seen gently dipping towards the sea, probably with the same inclination as when deposited round the ancient shores of the island. I found only one inland section, namely, at the base of the hill marked A, where, at the height of some hundred feet, this bed was exposed; it here rested on the usual compact augitic rock associated with wacke, and was covered by the widespread sheet of modern basaltic lava. Some exceptions occur to the horizontality of the white stratum: at Quail Island, its upper surface is only forty feet above the level of the sea; here also the capping of lava is only between twelve and fifteen feet in thickness; on the other hand, at the north-east side of Porto Praya harbour, the calcareous stratum, as well as the rock on which it rests, attain a height above the average level: the inequality of level in these two cases is not, as I believe, owing to unequal elevation, but to original irregularities at the bottom of the sea. Of this fact, at Quail Island, there was clear evidence in the calcareous deposit being in one part of much greater than the average thickness, and in another part being entirely absent; in this latter case, the modern basaltic lavas rested directly on those of more ancient origin.
Under Signal Post Hill, the white stratum dips into the sea in a remarkable manner. This hill is conical, 450 feet in height, and retains some traces of having had a crateriform structure; it is composed chiefly of matter erupted posteriorly to the elevation of the great basaltic plain, but partly of lava of apparently submarine origin and of considerable antiquity. The surrounding plain, as well as the eastern flank of this hill, has been worn into steep precipices, overhanging the sea. In these precipices, the white calcareous stratum may be seen, at the height of about seventy feet above the beach, running for some miles both northward and southward of the hill, in a line appearing to be perfectly horizontal; but for a space of a quarter of a mile directly under the hill, it dips into the sea and disappears. On the south side the dip is gradual, on the north side it is more abrupt, as is shown in Figure 2. As neither the calcareous stratum, nor the superincumbent basaltic lava (as far as the latter can be distinguished from the more modern ejections), appears to thicken as it dips, I infer that these