The Evolution of Photography. Werge John
the celebrated Swedish chemist, Scheele, formed the next interesting link between the simple and general blackening of a lump of chloride of silver, and the gradations of blackening which ultimately produced the photographic picture on a piece of paper possessing a prepared surface of nitrate of silver and chloride of sodium in combination. Scheele discovered in 1777 that the blackening of the silver compound was due to the reducing power of light, and that the black deposit was reduced silver; and it is precisely the same effect of the action of light upon chloride of silver passing through the various densities of the negative that produces the beautiful photographic prints with which we are all familiar at the present time. Scheele was also the first to discover and make known the fact that chloride of silver was blackened or reduced to various depths by the varying action of the prismatic colours. He fixed a glass prism in a window, allowed the refracted sunbeams to fall on a piece of paper strewn with luna cornua—fused chloride of silver—and saw that the violet ray was more active than any of the other colours. Anyone, with a piece of sensitised paper and a prism, or piece of a broken lustre, can repeat and see for themselves Scheele’s interesting discovery; and anyone that can draw a head or a flower may catch a sunbeam in a small magnifying glass, and make a drawing on sensitised paper with a pencil, as long as the sun is distant from the earth. It is the old story of Columbus and the egg—easy to do when you are shown or told how.
Charles William Scheele was born at Stralsund, Sweden, December 19th, 1742, and died at Koeping, on lake Moeler, May 21st, 1786. He was the real father of photography, for he produced the first photographic picture on record without camera and without lens, with the same chemical compound and the same beautiful and wonderful combination of natural colours which we now employ. Little did he dream what was to follow. But photography, like everything else in this world, is a process of evolution.
Senebier followed up Scheele’s experiments with the solar spectrum, and ascertained that chloride of silver was darkened by the violet ray in fifteen minutes, while the red rays were sluggish, and required twenty minutes to produce the same result.
John Wm. Ritter, born at Samitz, in Silesia, corroborated the experiments of Scheele, and discovered that chloride of silver was blackened beyond the spectrum on the violet side. He died in 1810; but he had observed what is now called the fluorescent rays of the spectrum—invisible rays which unquestionably exert themselves in the interests and practice of photography.
Many other experiments were made by other chemists and philosophers on the influence of light on various substances, but none of them had any direct bearing on the subject under consideration until Count Rumford, in 1798, communicated to the Royal Society his experiments with chloride of gold. Count Rumford wetted a piece of taffeta ribbon with a solution of chloride of gold, held it horizontally over the clear flame of a wax candle, and saw that the heat decomposed the gold solution, and stained the ribbon a beautiful purple. Though no revived gold was visible, the ribbon appeared to be coated with a rich purple enamel, which showed a metallic lustre of great brilliancy when viewed in the sunlight; but its photographic value lay in the circumstance of the hint it afterwards afforded M. Fizeau in applying a solution of chloride of gold, and, by means of heat, depositing a fine film of metallic gold on the surface of the Daguerreotype image, thereby increasing the brilliancy and permanency of that form of photographic picture. A modification of M. Fizeau’s chloride of gold “fixing process” is still used to tone, and imparts a rich purple colour to photographic prints on plain and albumenized papers.
In 1800, Dr. Herschel’s “Memoirs on the Heating Power of the Solar Spectrum” were published, and out of his observations on the various effects of differently coloured darkening glasses arose the idea that the chemical properties of the prismatic colours, and coloured glass, might be as different as those which related to heat and light. His suspicions were ultimately verified, and hence the use of yellow or ruby glass in the windows of the “dark room,” as either of those coloured glasses admit the luminous ray and restrain the violet or active photographic ray, and allow all the operations that would otherwise have to be performed in the dark, to be seen and done in comfort, and without injury to the sensitive film.
The researches of Dr. Wollaston, in 1802, had very little reference to photography beyond his examination of the chemical action of the rays of the spectrum, and his observation that the yellow stain of gum guaiacum was converted to a green colour in the violet rays, and that the red rays rapidly destroyed the green tint the violet rays had generated.
1802 is, however, a memorable year in the dark ages of photography, and the disappointment of those enthusiastic and indefatigable pursuers of the sunbeam must have been grievous indeed, when, after years of labour, they found the means of catching shadows as they fell, and discovered that they could not keep them.
Thomas Wedgwood, son of the celebrated potter, was not only the first that obtained photographic impressions of objects, but the first to make the attempt to obtain sun-pictures in the true sense of the word. Scheele had obtained the first photographic picture of the solar spectrum, but it was by accident, and while pursuing other chemical experiments; whereas Wedgwood went to work avowedly to make the sunbeam his slave, to enlist the sun into the service of art, and to compel the sun to illustrate art, and to depict nature more faithfully than art had ever imitated anything illumined by the sun before. How far he succeeded everyone should know, and no student of photography should ever tire of reading the first published account of his fascinating pastime or delightful vocation, if it were but to remind him of the treasures that surround him, and the value of hyposulphite of soda. What would Thomas Wedgwood not have given for a handful of that now common commodity? There is a mournfulness in the sentence relative to the evanescence of those sun-pictures in the Memoir by Wedgwood and Davy that is peculiarly impressive and desponding contrasted with our present notions of instability. We know that sun-pictures will, at the least, last for years, while they knew that at the most they would endure but for a few hours. The following extracts from the Memoir published in June, 1802, will, it is hoped, be found sufficiently interesting and in place here to justify their insertion.
“White paper, or white leather moistened with solution of nitrate of silver, undergoes no change when kept in a dark place, but on being exposed to the daylight it speedily changes colour, and after passing through different shades of grey and brown becomes at length nearly black.... In the direct beams of the sun, two or three minutes are sufficient to produce the full effect, in the shade several hours are required, and light transmitted through different coloured glasses acts upon it with different degrees of intensity. Thus it is found that red rays, or the common sunbeams passed through red glass, have very little action upon it; yellow and green are more efficacious, but blue and violet light produce the most decided and powerful effects.... When the shadow of any figure is thrown upon the prepared surface, the part concealed by it remains white, and the other parts speedily become dark. For copying paintings on glass, the solution should be applied on leather, and in this case it is more readily acted on than when paper is used. After the colour has been once fixed on the leather or paper, it cannot be removed by the application of water, or water and soap, and it is in a high degree permanent. The copy of a painting or the profile, immediately after being taken, must be kept in an obscure place; it may indeed be examined in the shade, but in this case the exposure should be only for a few minutes; by the light of candles or lamps as commonly employed it is not sensibly affected.
“No attempts that have been made to prevent the uncoloured parts of the copy or profile from being acted upon by the light have as yet been successful. They have been covered by a thin coating of fine varnish, but this has not destroyed their susceptibility of becoming coloured, and even after repeated washings, sufficient of the active part of the saline matter will adhere to the white parts of leather or paper to cause them to become dark when exposed to the rays of the sun....
“The images formed by means of a camera-obscura have been found to be too faint to produce, in any moderate time, an effect upon the nitrate of silver. To copy these images was the first object of Mr. Wedgwood, in his researches on the subject, and for this purpose he first used the nitrate of silver, which was mentioned to him by a friend, as a substance very sensible to the influence of light; but all his numerous experiments as to their primary end proved unsuccessful.”
From the foregoing extracts from the first lecture on photography that ever was delivered or published, it will be seen that