Applied Organic Chemistry. Surya K. De

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72.106 65 0.883 Soluble 7.52 Toluene C₇H₈ 92.14 110 0.867 0.05 2.38 Triethylamine C₆H₁₅N 101.19 89 0.728 0.02 2.4 Trifluoroacetic acid C₂HFO₂ 114.023 72 1.489 Miscible 8.55 2,2,2‐Trifluoroethanol C₂H₃F₃O 100.04 74 1.384 Miscible 8.56 Water H₂O 18.02 100 0.998 — 78.54 Water heavy D₂O 20.03 101 1.107 Miscible o‐Xylene C₈H₁₀ 106.17 144 0.897 Insoluble 2.57 m‐Xylene C₈H₁₀ 106.17 139 0.868 Insoluble 2.37 p‐Xylene C₈H₁₀ 106.17 138 0.861 Insoluble 2.27

References

      1. Professor Murov's Organic solvent table.

      2. Vogel's Practical Organic Chemistry.

      3. American Chemical Society, Organic Division.

List of Cooling Baths

Cooling agent	Organic solvent or inorganic salt	Temperature (°C)
Dry ice	1,4‐Dioxane	+12
Dry ice	Cyclohexane	+6
Dry ice	Benzene	+5
Dry ice	N,N‐Dimethylformamide	+2
Ice	Water	0

Cooling agent	Organic solvent or inorganic salt	Temperature (°C)
Liquid N2	Aniline	−6
Liquid N2	Ethylene glycol	−10
Liquid N2	Cycloheptane	−12
Dry ice	Benzyl alcohol	−15
Dry ice	Ethylene glycol	−15
Dry ice	Tetrahydrofuran	−22
Dry ice	Carbon tetrachloride	−23
Dry ice	1,3‐Dichlorobenzene	−25
Dry ice	o‐Xylene	−29
Liquid N2	Bromobenzene	−30
Dry ice	m‐Toluidine	−32
Dry ice	3‐Heptanone	−38
Dry ice	Pyridine	−42
Dry ice	Cyclohexanone	−46
Dry ice	Acetonitrile	−46
Dry ice	m‐Xylene	−47
Dry ice	Diethyl carbitol	−52
Dry ice	n‐Octane	−56
Dry ice	Diisopropyl ether	−60
Dry ice	Trichloroethylene	−73
Dry ice	Isopropyl alcohol	−77
Liquid N2	Butyl acetate Скачать книгу