Quantum Mechanics, Volume 3. Claude Cohen-Tannoudji

Quantum Mechanics, Volume 3 - Claude Cohen-Tannoudji


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operator W2 (1,2) is symmetric (particles 1 and 2 play an equivalent role). The factor 1/2 in image disappears and we get:

      (70)image

      We can regroup these two contributions, using the fact that for any operator O(12), it can be shown that:

      (72)image

      Now, for any operator O(1), we can write:

      The term in eiχ has a similar form, but it does not have to be computed for the following reason. The variation image is the sum of a term in eiχ and another in e–iχ:

      (76)image

       β. Variation of the energies

      Let us now see what happens if the energy image varies by image. The function image then varies by image which, according to relation (40), induces a variation of image:

      and thus leads to variations of expressions (61) of image and image. Their sum is:

      (79)image

      (80)image

      As for image, its variation is the sum of a term in image coming from the explicit presence of the energies image in its definition (61), and a term in image. If we let only the energy image vary (not taking into account the variations of the distribution function), we get a zero result, since:

      (81)image

      Consequently, we just have to vary by image the distribution function, and we get:

      (82)image

      Finally, after simplification by image (which, by hypothesis, is different from zero), imposing the variation image to be zero leads to the condition: