Methodologies in Amine Synthesis. Группа авторов
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Table of Contents
1 Cover
4 Preface
5 1 Substitution‐type Electrophilic Amination Using Hydroxylamine‐Derived Reagents 1.1 Introduction 1.2 Cu‐Catalyzed Reactions 1.3 Electrophilic Amination Reactions Catalyzed by Other Transition Metals 1.4 Electrophilic Amination with Hydroxylamine‐derived Metallanitrenes 1.5 Transition‐Metal‐Free Electrophilic Amination Reactions 1.6 Conclusion References
6 2 Remote Functionalizations Using Nitrogen Radicals in H‐Atom Transfer (HAT) Reactions 2.1 Introduction 2.2 Intramolecular 1,5‐H‐Atom Transfer (1,5‐HAT) 2.3 Photoinduced Strategies 2.4 Thermal Strategies 2.5 Summary and Conclusions References
7 3 Radical‐Based C—N Bond Formation in Photo/Electrochemistry 3.1 Introduction 3.2 C—N Bond Formation via N‐radical Species Addition 3.3 Amination via N‐atom Nucleophilic Addition 3.4 Amination via Radical Cross‐coupling 3.5 Summary and Conclusions References
8 4 Propargylamines: Recent Advances in Asymmetric Synthesis and Use as Chemical Tools in Organic Chemistry 4.1 Introduction 4.2 Metal‐Catalyzed Asymmetric Synthesis of Propargylamines 4.3 Enzymatic Synthesis of Propargylamines 4.4 Photoredox Synthesis of Propargylamines 4.5 Organocatalyzed Asymmetric Synthesis of Propargylamines 4.6 Propargylamines as Building Blocks in the Synthesis of Heterocycles 4.7 Conclusions References
9 5 Transition‐Metal‐Catalyzed Chiral Amines Synthesis 5.1 Introduction 5.2 Asymmetric Reductive Amination 5.3 Asymmetric Hydroamination 5.4 Asymmetric Hydroaminoalkylation 5.5 Asymmetric Hydroaminomethylation 5.6 Coupling on a Chiral Metal Center 5.7 Conclusion References
10 6 Industrial Relevance of Asymmetric Organocatalysis in the Preparation of Chiral Amine Derivatives 6.1 Introduction 6.2 Organocatalysis in Manufacture: Representative Examples 6.3 Case Studies 6.4 Summary and Conclusions References Note
11 7 Biocatalytic Synthesis of Chiral Amines Using Oxidoreductases 7.1 Introduction 7.2 Amine Oxidases 7.3 Amine Dehydrogenases 7.4 Imine Reductases 7.5 Engineered Cytochrome P450s 7.6 Conclusions and Perspectives References
12 8 Engineering Functional Nanomaterials Through the Amino Group 8.1 Introduction 8.2 Quantification of Nanomaterial‐Bound Amino Groups 8.3 Exploiting Amino Compounds for the Functionalization of Carbon‐Based Nanomaterials 8.4 Amines in the Synthesis and Functionalization of Carbon Dots 8.5 Amines for the Engineering of Hybrid Organic–Inorganic Nanomaterials References
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