Liquid Crystals. Iam-Choon Khoo

Liquid Crystals

constants and refractive indices, as well as electrical conductivities of liquid crystals, are physical parameters that characterize the electronic responses of liquid crystals to externally applied fields (electric, magnetic, or optical). Because of the molecular and energy level structures of nematic molecules, these responses are highly dependent on the direction and the frequencies of the field. Accordingly, we shall classify our studies of dielectric permittivity and other electro‐optical parameters into two distinctive frequency regimes: (1) dc and low frequency and (2) optical frequency. Where the transition from the regime (1) to (2) occurs, of course, is governed by the dielectric relaxation processes and the dynamical time constant; typically, the Debye relaxation frequencies in nematics are on the order of 10¹⁰ Hz.

3.3.1. DC and Low‐frequency Dielectric Permittivity, Conductivities, and Magnetic Susceptibility

The dielectric constant ε is defined by the Maxwell equation [5]:

(3.15a) ModifyingAbove upper D With right harpoon with barb up equals ModifyingAbove Above ModifyingAbove epsilon With right harpoon with barb up With right harpoon with barb up dot ModifyingAbove upper E With right harpoon with barb up comma

where ModifyingAbove upper D With right harpoon with barb up is the displacement current, ModifyingAbove upper E With right harpoon with barb up is the electric field, and ModifyingAbove Above ModifyingAbove epsilon With right harpoon with barb up With right harpoon with barb up is the tensor. For a uniaxial nematic liquid crystal, we have

(3.15b) ModifyingAbove Above ModifyingAbove epsilon With right harpoon with barb up With right harpoon with barb up equals Start 3 By 3 Matrix 1st Row 1st Column epsilon Subscript up-tack Baseline 2nd Column 0 3rd Column 0 2nd Row 1st Column 0 2nd Column epsilon Subscript up-tack Baseline 3rd Column 0 3rd Row 1st Column 0 2nd Column 0 3rd Column epsilon Subscript parallel-to Baseline EndMatrix period

Equations (3.15a) and (3.15b) yield, for the two principal axes,

(3.16) upper D Subscript parallel-to Baseline equals epsilon Subscript parallel-to Baseline upper E Subscript parallel-to

and

(3.17) upper D Subscript up-tack Baseline equals epsilon Subscript up-tack Baseline upper E Subscript up-tack Baseline period

Typical values of ε_|| and ε_⊥ are on the order of 5ε₀, where ε₀ is the permittivity of free space. Similarly, the electric conductivities σ_|| and σ_⊥ of nematics are defined by

(3.18) upper J Subscript parallel-to Baseline equals sigma Subscript parallel-to Baseline upper E Subscript parallel-to

and

(3.19) upper J Subscript up-tack Baseline equals sigma Subscript up-tack Baseline upper E Subscript up-tack Baseline comma

where J_∥ and J_⊥ are the currents flowing along and perpendicularly to the director axis, respectively. In conjunction with an applied dc electric field, the conductivity anisotropy could give rise to space charge accumulation and create strong director axis reorientation in a nematic film, giving rise to an orientational photorefractive [6] effect (see Chapter 8).

Most nematics (e.g. E7, pentyl cyanobiphenyl [5CB], etc.) are said to possess positive (dielectric) anisotropy (ε_|| > ε_⊥). On the other hand, some nematics, such as MBBA, possess negative anisotropy (i.e. ε_|| < ε_⊥). The controlling factors are the molecular constituents and structures.

In general, ε_|| and ε_⊥ have different dispersion regions, as shown in Figure 3.4 for 4‐methoxy‐4′‐n‐butylazoxy‐benzene [7], which possess negative dielectric anisotropy (Δε < 0). Also plotted in Figure 3.4 is the dispersion of ε_iso, the dielectric constant for the isotropic case. Notice that for frequencies of 10⁹ Hz or less, ε_⊥ > ε_||. At higher frequencies and in the optical regime, ε_|| > ε_⊥ (i.e. the dielectric anisotropy changes sign).

For some nematic liquid crystals, this changeover in the sign of Δε = ε_|| − ε_⊥ occurs at a much lower frequency (cf. Figure 3.5 for phenylbenzoates [8]). This changeover frequency f_co is lower because of the long three‐ringed molecular structure, which is highly resistant to the rotation of molecules around the short axes.

Image described by caption.

Figure 3.4. Dispersion data of the dielectric constant ε_|| and ε_⊥ for the nematic and isotropic phase of the liquid crystal 4‐methoxy‐4′‐n‐butylazoxy‐benzene.

Figure 3.5. Dispersion data of the dielectric constant ε_|| and ε_⊥ for the nematic and isotropic phase of the liquid crystal phenylbenzoate.

For electro‐optical applications, the dielectric relaxation behavior of ε_|| and ε_⊥ for the different classes of nematic liquid crystals, and the relationships between the molecular structures and the dielectric constant, is obviously very important. This topic, however, is beyond the scope of this chapter, and the reader is referred to Blinov [8] and Khoo and Wu [9] and the references quoted therein for more detailed information.

Pure organic liquids are dielectric (i.e. nonconducting [σ = 0]). The electric conductivities of liquid crystals are due to some impurities or ions. In general, σ_|| is larger than σ_⊥. Electrical conduction plays an important role in electro‐optical applications of liquid crystals in terms of stability and instability, chemical degradation, and lifetime of the device [9]. Typically, σ_|| and σ_⊥ are on the order of 10⁻¹⁰ S⁻¹ cm⁻¹ for pure nematics. As in almost all materials, these conductivities could be varied by several orders of magnitude with the use of appropriate dopants.

The magnetic susceptibility of a material is defined in terms of the magnetization Скачать книгу