Remote C-H Bond Functionalizations. Группа авторов

Remote C-H Bond Functionalizations - Группа авторов


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      Source: Modified from Wan et al. [18].

Chemical reaction depicts the meta-C–H arylation of hydrocinnamic acids with aryl iodides.

      Source: Modified from Li et al. [15].

      Finally, C–H deuteration and alkylation of hydrocinnamic acid derivatives were also possible using N‐based heteroarene‐containing templates, but only isolated examples were disclosed [19]. In short, the notable meta‐C–H activation hydrocinnamic acid derivatives includes olefination and arylation with Pd(II) or Rh(III) catalysts, using nitrile‐based or carboxyl‐based templates.

      2.2.2.2 Phenylacetic Acid Derivatives

Chemical reaction depicts the meta-C–H olefination of phenylacetate.

      Source: Modified from Bera et al. [20].

Chemical reaction depicts the meta-C–H olefination of phenylacetic acid derivatives. Chemical reaction depicts the Rh-catalyzed meta-C–H olefination of phenylacetic acid derivatives.

      Source: Modified from Bera et al. [22].

Chemical reaction depicts the Pyridine-based template assisted meta-C–H olefination of phenylacetic acid derivatives.

      Source: Modified from Jin et al. [23].

Chemical reaction depicts the (a) meta-C-H perfluoroalkenylation of phenylacetic acid derivatives. (b) meta-C-H alkenylation of phenylacetic acid derivatives with electron-deficient coupling partners.

      Source: (a) Modified from Brochetta et al. [24]; (b) Modified from Jiao et al. [25].

      Meanwhile, Wang, Zhou, and


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