Remote C-H Bond Functionalizations. Группа авторов

Remote C-H Bond Functionalizations - Группа авторов


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of MPAA ligand Ac‐Val‐OH. Finally, it was believed that the dialogue between synthetic and computational chemistry groups might inspire the development of novel templates for remote C–H activation.

Chemical reaction depicts the meta-C–H olefination of benzoic acid derivatives with conformationally flexible nitrile-based template.

      Source: Modified from Fang et al. [29].

      2.2.3 Amine and N‐Heterocyclic Arene Derivatives

      2.2.3.1 Aniline Derivatives

Chemical reaction depicts the meta-C–H olefination of aniline derivatives. Chemical reaction depicts the (a) synthesis of substrate from CO2 for meta-C–H activation of aniline. (b) meta-C–H olefination of aniline carbamates.

      Source: (a) Modified from Yang et al. [32].

Chemical reaction depicts the meta-C–H olefination of tertiary anilines. Chemical reaction depicts the (a) meta-C–H acetoxylation of aniline amides. (b) meta-C–H acetoxylation of aniline carbamates.

      Source: (a) Modified from Tang et al. [31]; (b) Modified from Yang et al. [32].

      2.2.3.2 Benzylamine Derivatives

Chemical reaction depicts the meta-C–H acetoxylation of benzylamine derivatives.

      Source: Modified from Tang et al. [31].

Chemical reaction depicts the meta-C–H olefination of tertiary benzylamines and distal arene-tethered tertiary amine derivatives.
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