Essays: Scientific, Political, & Speculative (Vol. 1-3). Spencer Herbert

      ADDENDA.

       Table of Contents

      Speculative as is much of the foregoing essay, it appears undesirable to include in it anything still more speculative. For this reason I have decided to set forth separately some views concerning the genesis of the so-called elements during nebular condensation, and concerning the accompanying physical effects. At the same time it has seemed best to detach from the essay some of the more debatable conclusions originally contained in it; so that its general argument may not be needlessly implicated with them. These new portions, together with the old portions which re-appear more or less modified, I here append in a series of notes.

      Note I. For the belief that the so-called elements are compound there are both special reasons and general reasons. Among the special may be named the parallelism between allotropy and isomerism; the numerous lines in the spectrum of each element; and the cyclical law of Newlands and Mendeljeff. Of the more general reasons, which, as distinguished from these chemical or chemico-physical ones, may fitly be called cosmical, the following are the chief.

      The general law of evolution, if it does not actually involve the conclusion that the so-called elements are compounds, yet affords a priori ground for suspecting that they are such. The implication is that, while the matter composing the Solar System has progressed physically from that relatively-homogeneous state which it had as a nebula to that relatively-heterogeneous state presented by Sun, planets, and satellites, it has also progressed chemically, from the relatively-homogeneous state in which it was composed of one or a few types of matter, to that relatively-heterogeneous state in which it is composed of many types of matter very diverse in their properties. This deduction from the law which holds throughout the cosmos as now known to us, would have much weight even were it unsupported by induction; but a survey of chemical phenomena at large discloses several groups of inductive evidences supporting it.

      The first is that since the cooling of the Earth reached an advanced stage, the components of its crust have been ever increasing in heterogeneity. When the so-called elements, originally existing in a dissociated state, united into oxides, acids, and other binary compounds, the total number of different substances was immensely augmented, the new substances were more complex than the old, and their properties were more varied. That is, the assemblage became more heterogeneous in its kinds, in the composition of each kind, and in the range of chemical characters. When, at a later period, there arose salts and other compounds of similar degrees of complexity, there was again an increase of heterogeneity, alike in the aggregate and in its members. And when, still later, matters classed as organic became possible, the multiformity was yet further augmented in kindred ways. If, then, chemical evolution, so far as we can trace it, has been from the homogeneous to the heterogeneous, may we not fairly suppose that it has been so from the beginning? If, from late stages in the Earth's history, we run back, and find the lines of chemical evolution continually converging, until they bring us to bodies which we cannot decompose, may we not suspect that, could we run back these lines still further, we should come to still decreasing heterogeneity in the number and nature of the substances, until we reached something like homogeneity?

      A parallel argument may be derived from consideration of the affinities and stabilities of chemical compounds. Beginning with the complex nitrogenous bodies out of which living things are formed, and which, in the history of the Earth, are the most modern, at the same time that they are the most heterogeneous, we see that the affinities and stabilities of these are extremely small. Their molecules do not enter bodily into union with those of other substances so as to form more complex compounds still, and their components often fail to hold together under ordinary conditions. A stage lower in degree of composition we come to the vast assemblage of oxy-hydro-carbons, numbers of which show many and decided affinities, and are stable at common temperatures. Passing to the inorganic group, we are shown by the salts &c. strong affinities between their components and unions which are, in many cases, not very easily broken. And then when we come to the oxides, acids, and other binary compounds, we see that in many cases the elements of which they are formed, when brought into the presence of one another under favourable conditions, unite with violence; and that many of their unions cannot be dissolved by heat alone. If, then, as we go back from the most modern and most complex substances to the most ancient and simplest substances, we see, on the average, a great increase in affinity and stability, it results that if the same law holds with the simplest substances known to us, the components of these, if they are compound, may be assumed to have united with affinities far more intense than any we have experience of, and to cling together with tenacities far exceeding the tenacities with which chemistry acquaints us. Hence the existence of a class of substances which are undecomposable and therefore seem simple, appears to be an implication; and the corollary is that these were formed during early stages of terrestrial concentration, under conditions of heat and pressure which we cannot now parallel.

      Yet another support for the belief that the so-called elements are compounds, is derived from a comparison of them, considered as an aggregate ascending in their molecular weights, with the aggregate of bodies known to be compound, similarly considered in their ascending molecular weights. Contrast