Essays: Scientific, Political, & Speculative (Vol. 1-3). Spencer Herbert
as a class with the quaternary compounds as a class. The molecules constituting oxides (whether alkaline or acid or neutral) chlorides, sulphurets, &c. are relatively small; and, combining with great avidity, form stable compounds. On the other hand, the molecules constituting nitrogenous bodies are relatively vast and are chemically inert; and such combinations as their simpler types enter into, cannot withstand disturbing forces. Now a like difference is seen if we contrast with one another the so-called elements. Those of relatively-low molecular weights—oxygen, hydrogen, potassium, sodium, &c.—show great readiness to unite among themselves; and, indeed, many of them cannot be prevented from uniting under ordinary conditions. Contrariwise, under ordinary conditions the substances of high molecular weights—the "noble metals"—are indifferent to other substances; and such compounds as they do form under conditions specially adjusted, are easily destroyed. Thus as, among the bodies we know to be compound, increasing molecular weight is associated with the appearance of certain characters, and as, among the bodies we class as simple, increasing molecular weight is associated with the appearance of similar characters, the composite nature of the elements is in another way pointed to.
There has to be added one further class of phenomena, congruous with those above named, which here specially concerns us. Looking generally at chemical unions, we see that the heat evolved usually decreases as the degree of composition, and consequent massiveness, of the molecules, increases. In the first place, we have the fact that during the formation of simple compounds the heat evolved is much greater than that which is evolved during the formation of complex compounds: the elements, when uniting with one another, usually give out much heat; while, when the compounds they form are recompounded, but little heat is given out; and, as shown by the experiments of Prof. Andrews, the heat given out during the union of acids and bases is habitually smaller where the molecular weight of the base is greater. Then, in the second place, we see that among the elements themselves, the unions of those having low molecular weights result in far more heat than do the unions of those having high molecular weights. If we proceed on the supposition that the so-called elements are compounds, and if this law, if not universal, holds of undecomposable substances as of decomposable, then there are two implications. The one is that those compoundings and recompoundings by which the elements were formed, must have been accompanied by degrees of heat exceeding any degrees of heat known to us. The other is that among these compoundings and recompoundings themselves, those by which the small-moleculed elements were formed produced more intense heat than those by which the large-moleculed elements were formed: the elements formed by the final recompoundings being necessarily later in origin, and at the same time less stable, than the earlier-formed ones.
Note II. May we from these propositions, and especially from the last, draw any conclusions respecting the evolution of heat during nebular condensation? And do such conclusions affect in any way the conclusions now current?
In the first place, it seems inferable from physico-chemical facts at large, that only through the instrumentality of those combinations which formed the elements, did the concentration of diffused nebulous matter into concrete masses become possible. If we remember that hydrogen and oxygen in their uncombined states oppose, the one an insuperable and the other an almost insuperable, resistance to liquefaction, while when combined the compound assumes the liquid state with facility, we may suspect that in like manner the simpler types of matter out of which the elements were formed, could not have been reduced even to such degrees of density as the known gases show us, without what we may call proto-chemical unions: the implication being that after the heat resulting from each of such proto-chemical unions had escaped, mutual gravitation of the parts was able to produce further condensation of the nebulous mass.
If we thus distinguish between the two sources of heat accompanying nebular condensation—the heat due to proto-chemical combinations and that due to the contraction caused by gravitation (both of them, however, being interpretable as consequent on loss of motion), it may be inferred that they take different shares during the earlier and during the later stages of aggregation. It seems probable that while the diffusion is great and the force of mutual gravitation small, the chief source of heat is combination of units of matter, simpler than any known to us, into such units of matter as those we know; while, conversely, when there has been reached close aggregation, the chief source of heat is gravitation, with consequent pressure and gradual contraction. Supposing this to be so, let us ask what may be inferred. If at the time when the nebulous spheroid from which the Solar System resulted, filled the orbit of Neptune, it had reached such a degree of density as enabled those units of matter which compose the sodium molecules to enter into combination; and if, in conformity with the analogies above indicated, the heat evolved by this proto-chemical combination was great compared with the heats evolved by the chemical combinations known to us; the implication is that the nebulous spheroid, in the course of its contraction, would have to get rid of a much larger quantity of heat than it would, did it commence at any ordinary temperature and had only to lose the heat consequent on contraction. That is to say, in estimating the past period during which solar emission of heat has been going on at a high rate, much must depend on the initial temperature assumed; and this may have been rendered intense by the proto-chemical changes which took place in early stages.[21]
Respecting the future duration of the solar heat, there must also be differences between the estimates made according as we do or do not take into account the proto-chemical changes which possibly have still to take place. True as it may be that the quantity of heat to be emitted is measured by the quantity of motion to be lost, and that this must be the same whether the approximation of the molecules is effected by chemical unions, or by mutual gravitation, or by both; yet, evidently, everything must turn on the degree of condensation supposed to be eventually reached; and this must in large measure depend on the natures of the substances eventually formed. Though, by spectrum-analysis, platinum has recently been detected in the solar atmosphere, it seems clear that the metals of low molecular weights greatly predominate; and supposing the foregoing arguments to be valid, it may be inferred, as not improbable, that the compoundings and recompoundings by which the heavy-moleculed elements are produced, not hitherto possible in large measure, will hereafter take place; and that, as a result, the Sun's density will finally become very great in comparison with what it is now. I say "not hitherto possible in large measure", because it is a feasible supposition that they may be formed, and can continue to exist, only in certain outer parts of the Solar mass, where the pressure is sufficiently great while the heat is not too great. And if this be so, the implication is that the interior body of the Sun, higher in temperature than its peripheral layers, may consist wholly of the metals of low atomic weights, and that this may be a part cause of his low specific gravity; and a further implication is that when, in course of time, the internal temperature falls, the heavy-moleculed elements, as they severally become capable of existing in it, may arise: the formation of each having an evolution of heat as its concomitant.[22] If so, it would seem to follow that the amount of heat to be emitted by the Sun, and the length of the period during which the emission will go on, must be taken as much greater than if the Sun is supposed to be permanently constituted of the elements now predominating in him, and to be capable of only that degree of condensation which such composition permits.
Note III. Are the internal structures of celestial bodies all the same, or do they differ? And if they differ, can we, from the process of nebular condensation, infer the conditions under which they assume one or other character? In the foregoing essay as originally published, these questions were discussed; and though the conclusions reached cannot be sustained in the form given to them, they foreshadow conclusions which may, perhaps, be sustained. Referring to the conceivable causes of unlike specific gravities in the members of the solar system, it was said that these might be—
"1. Differences between the kinds of matter or matters composing them. 2. Differences between the quantities of matter; for, other things equal, the mutual gravitation of atoms will make a large mass denser than a small one. 3. Differences between the structures: the masses being either solid or liquid throughout, or having central cavities filled with elastic aëriform substance. Of these three conceivable causes, that commonly assigned is the first, more or less modified by the second."
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