CO2 Hydrogenation Catalysis. Группа авторов

CO2 Hydrogenation Catalysis

of graphitic carbon nitride (circled part...Figure 7.5 Possible reaction mechanism for bicarbonate hydrogenation over Pd...Figure 7.6 (a) Synthetic approaches to tailor the basic properties of g‐C₃N₄ Figure 7.7 (A) FT‐IR spectra of Au/Al₂O₃ catalyst treated with (a) DMF/NEt₃ ...Figure 7.8 (a) Comparison of the catalytic activities of a series of support...Figure 7.9 (a) Possible reaction mechanism for CO₂ hydrogenation to formic a...Figure 7.10 (a) Schematic illustration for the preparation of PdAg/SBA‐15‐Am...Figure 7.11 Proposed synergistic mechanism for the hydrogenation of CO₂ to f...Figure 7.12 Ru K‐edge FT‐EXAFS spectra and schematic illustration of Ru/LDH....Figure 7.13 (a) Relationship between TON‐based on Ru during CO₂ hydrogenatio...Figure 7.14 Energy profile for CO₂ hydrogenation to formic acid on Cu‐dG. Di...

8 Chapter 8Figure 8.1 Schematic diagrams of the CAMERE process; (a) the original proces...Figure 8.2 The “George Olah Carbon Dioxide to Renewable Methanol Plant” of C...Figure 8.3 Liquid formation in a view cell during methanol synthesis of H₂, ...Figure 8.4 Equilibrium CO₂ conversion and methanol selectivity at different ...Figure 8.5 Types of catalyst material reported for CO₂ hydrogenation to meth...Figure 8.6 Synthesis methods of Cu/ZnO‐based catalysts. The percentage was c...Figure 8.7 Schematic overview of the multistep synthesis route for Cu/ZnO ca...Figure 8.8 Simplified preparation scheme of Cu/ZnO catalyst from zincian mal...Figure 8.9 Microstructural features revealed with transmission electron micr...Figure 8.10 General scheme for methanol synthesis over Cu/ZnO‐based catalyst...Figure 8.11 Proposed reaction mechanisms for the CO₂ hydrogenation toward me...Figure 8.12 Proposed reaction mechanisms for the CO₂ hydrogenation toward et...

9 Chapter 9Figure 9.1 Line drawings of (a) [M(bpy)₂X₂]⁺, (b) M(Cp*)(bpy)Cl]⁺, (c) [Rh(d...Figure 9.2 Line drawings of (a) [Ir(POCOP)H₂(MeCN)]⁺, (b) [Ir(POCOP)′H₂(MeCN...Figure 9.3 Line drawings of [IrCp*(L)(X)]ⁿ⁺, where L is varied.Figure 9.4 Line drawings of (a) [Ru(bpy)₂(CO)₂]²⁺, (b) [Os(bpy)(CO)H]⁺, (c) ...Figure 9.5 Line drawings of (a) [Fe(dophen)L₂]⁺, (b) [Fe(^tBudhbpy)Cl], (c) [...Figure 9.6 Line drawings of (a) [Ni(cyclam)]²⁺, (b) [Ni₂(biscyclam)]⁴⁺, and ...Figure 9.7 Line drawings of [Ni(2H‐qpdt^x)₂)] x = a, b, c.Figure 9.8 Line drawings of (a) [Fe₆Mo₂S₈(SEt)₈]³⁻, (b) [Fe₄S₄(SR)₄]²⁻...Figure 9.9 Terminal hydride insertion pathways.Figure 9.10 Bridging hydride insertion pathways.Figure 9.11 Electrocatalytic reduction of CO₂ to formate by [Co(P^R ₂N^R′ Figure 9.12 Electrocatalytic reduction of CO₂ to formate with [Ir(PN^HP)H₃]....Figure 9.13 Electrocatalytic reduction of CO₂ to formate with [Fe₄N(CO)₁₂]⁻...Figure 9.14 Definition of hydricity.Figure 9.15 Driving force for hydride transfer between L_n‐M and CO₂.Figure 9.16 Line drawings and hydricity of (a) H‐[Fe₄N(CO)₁₂]⁻, (b) H‐...Figure 9.17 Electrochemical reduction of CO₂ to methanol using [Fe(PP₃)(MeCN...

10 Chapter 10Figure 10.1 Schematic representation of the setup used for continuous hydrog...Chart 10.1 Ru catalysts for FA dehydrogenation.Chart 10.2 Ligand structures of rac‐P4 and meso‐P4.Chart 10.3 Pincer ruthenium complex for FA dehydrogenation.Figure 10.2 Reaction mechanism for Ru‐4.Chart 10.4 Selective Ir catalysts for FA dehydrogenation.Figure 10.3 Reaction mechanism of FA dehydrogenation (FADH) via Ir‐2....Figure 10.4 Plausible reaction mechanism of bisMETAMORPhos catalyst, Ir‐3...Figure 10.5 Proposed mechanism for FA dehydrogenation using Fe/PP₃ catalysis...Chart 10.5 Selective well‐defined iron catalysts.Figure 10.6 Proposed reaction mechanism for FA dehydrogenation using an iron...Chart 10.6 Water‐soluble phosphine ligands for aqueous FA dehydrogenation wi...Figure 10.7 Hammett plots of FA dehydrogenation with Cp*Ir catalysts bearing...Chart 10.7 Selective Ir catalysts for FA dehydrogenation.Figure 10.8 Time courses of the volume and rate of released gases via FA deh...Figure 10.9 Time courses of volume of released gases (left axis) and rate of...Chart 10.8 Catalyst structures for MeOH dehydrogenation.Figure 10.10 Plausible reaction mechanism for methanol dehydrogenation.Figure 10.11 Proposed reaction mechanism for MeOH dehydrogenation using Ru‐6...Figure 10.12 Proposed reaction mechanism for MeOH dehydrogenation usingIr‐15...Figure 10.13 Proposed reaction mechanism for MeOH dehydrogenation using Fe ‐4...