|
Ni/TiO2 | Ru/TiO2 | 2019 |
|
Sol-gel | Wet-Impregnation
|
Sun light | Visible light
|
pH (natural)| 330 min (IMI) | 480 min (ATP, TMX)
|
IMI | ATP | TMX | 100% (Insecticides)
|
Solar (UV) > visible | Degraded products CO2 | H2O | ·OH
|
[191]
|
|
ZnO/G/TiO2 (ZGT) | 2016
|
Solvothermal
|
Ultrasonic
|
pH (9) | 120 min
|
MB | TBAC-L | TBBU-L TNFW-L | 4
|
Contributors: ·O2−, ·OH | π - π interaction
|
[192]
|
|
Zn-TCPP/Ag-TiO2 | 2016
|
Sol-gel
|
UV | Visible
|
-| 30 min
|
MB | PNP | 4
|
Enhancer-Porphyrin | 3.28 eV (bandgap)
|
[193]
|
|
Bi2S3/TiO2-Mt | 2018
|
Ion exchange | Impregnation
|
Near UV–Vis-light
|
pH (11) | 120 min
|
KP (80%) | -
|
Langmuir-Hinshelwood | pseudo-1st-order | ·O2− | ·OH
|
[194]
|
|
3D-g-C3N4-NS/TiO2-NF | 2018
|
Electrospinning | Thermal redox
|
Visible light >420nm
|
- | 120 min
|
Rh B (~93%) | 3
|
Activator ·O2− | pseudo-1st-order |
|
[195]
|
|
FeNi 3@SiO2@TiO2 | 2018
|
Sol-gel
|
UV-light
|
pH (9) | 200 min
|
TC (100%) | 5
|
Contributor ·OH |pseudo-1st-order |
|
[196]
|
|
Co3O4/TiO2/GO/amine | 2017
|
Sol-gel | Hydrothermal
|
Solar | Visible light
|
- | 90 min |
|
OTC (91%) |CR (91%) |5
|
Contributors e · OH, ·O2− CB, h+VB,−
|
[197]
|
|
CuInS2/Bi2WO6 | 2019
|
Hydrothermal
|
Visible light
|
| 120 min
|
TCH (92.4%) | 4
|
Activators: ·O2−, ·OH | Z-scheme
|
[198]
|
|
3D RGO-based hydrogel
|
Self-assembly | Reduction
|
UV-VIS
|
pH (2/3/(acidic) | 120 min
|
NPX | IBP | DFC | (70-80%) |
|
Langmuir | Freundlich | π-π interaction | pseudo-2nd-order
|
[199]
|
|
CQDs/TCNCs
|
Hydrothermal | Adsorption-polymerization
|
Visible light
|
pH (basic) | 30 min
|
TOC (22%) | CBZ (100 - 87.6%) | 4
|
5 times > pure TCN | Fukui index (fo = 0.108) olefinic (double bond)
|
[200]
|
|
PM-CQD/TiO2 (M: Ag/Au)
|
Green synthesis | Reduction
|
UV-VIS (MB) | Solar light (Drug)
|
- | 20 min | M: Ag 60 min | M: Au 108 min
|
MB (~96%) | Erythromycin (~100%) | Several
|
Superoxide ·O2−, | pseudo-1st-order
|
[201]
|
|
BiVO 4/N-CQDs/Ag3PO4
|
Solvothermal precipitation
|
Visible light
|
- | 30 min | 90 min
|
TC (88.9%) | TOC (59.8%) | 5
|
· O2− > h+ > ·OH | pseudo-1st-order | pseudo-2ndorder | Z-scheme
|
[202]
|
|
ZnO/N, S-CQDs | (Capping agent: (Try/Glu))
|
Hydrothermal
|
Visible |near-IR | Sun-light
|
- | 20–180 min
|
MB | RhB | MG | CEL | CIP (92.9%, 85.8%) | 5
|
Activator: ·O2− |pseudo-1st-order |
|
[203]
|
|
3D CQDs/TiO2/GO - PUF
|
Hydrothermal
|
Visible light
|
- | 1–6 h
|
MB | RhB | 5
|
Contributors: · O2− , ·OH
|
[204]
|
|
r-Mg-N-CD
|
Green Synthesis
|
Sun light
|
- | 120 min
|
MB (99.1%) | 4
|
·O2−, h+, ·OH | Langmuir Hinshelwood| 1st - order
|
[205]
|
|
ZnS QD (Capping agent: (L-Cys/2-ME))
|
Sonochemical | Chemical precipitation
|
UV light
|
11 | 90 min
|
CV (98.5%, 97.0%) | 5
|
Langmuir-Hinshelwood | pseudo-1st-order
|
[206]
|
|
f-MWCNTS-CdS QDs | f-MWCNTS-Ag2S QDs | (Capping agent - PAMAM)
|
Sonochemical | Grafting
|
UV
|
- | 1h
|
MO | -
|
Langmuir-Hinshelwood | 1st-order rate constant
|
[207]
|
|
NH2-functionalized GQD-TiO2
|
Molecular fusion | Hydrothermal
|
Visible light
|
- | 120 min
|
MO (96.0%) | 4
|
Contributors: h+ (44.7%), ·O2− (38.0%,), ·OH (17.3%)
|
[208]
|
M-ZnS QDs (M: Cu2+, Mn2+, Ag+)
|
